Bis(trimethyl­phenyl­ammonium) μ-oxalato-bis­[oxidodiperoxido­molybdate(VI)]

نویسندگان

  • Ayaka Oba
  • Masato Hashimoto
چکیده

A trimethyl-phenyl-ammonium salt of a dinuclear μ-oxalate complex of diperoxidomonomolybdate units, (C9H14N)2[Mo2(C2O4)(O2)4O2], was obtained from an acidic aqueous solution; the dianion is located about a centre of inversion. Each Mo atom bears two peroxide groups together with one O atom from the oxalate group in its equatorial positions and one terminal O atom as well as another O atom from the oxalate in axial positions. The oxalate group acts as a tetra-dentate bridging ligand and bridges between the diperoxidomolybdate units.

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012